Address book
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ANTONELLA GLISENTI
Position
Professoressa Ordinaria
Structure
Address
VIA F. MARZOLO, 1 - PADOVA
Telephone
0498275176
Prof. Antonella Glisenti
1988: Master in Chemistry (University of Padova);
1988: Research activity in Historic Material Conservation;
1993: PhD in Chemical Science;
1993-1994: post-doc research activity in the Advanced Magnetic Recording Laboratory (IBM San Jose - CA);
1994: Researcher (Department of Chemical Science – University of Padova);
2008 Master in Architecture (IUAV Venice)
2010: Professor of Inorganic Chemistry (Department of Chemical Science – University of Padova).
2018: Eligibility as Full Professor in Inorganic Chemistry and Industrial Chemistry
Research activity focuses on the development of oxide based advanced functional materials. Particular attention is devoted to the green processes with the aim of developing oxide based materials. Research activity mainly concerns design, synthesis and characterization of oxide based nano-materials and nano-composites (perovskites, transition metal oxides, ...) for application in the field of sustainable development (Fuel Cells, pollutants abatement).
1. New Advanced Electrodes for Intermediate Temperature Solid Oxide Fuel Cells (SOFCs) and Solid Oxide Electrolysis Cells (SOECs);
2. Platinum Group Metals free catalysts for Three Way Catalysts
3. Development of sustainable catalysts for green hydrogen production (alcohol steam reforming and oxidative steam reforming, dry reforming).
Nano-materials, synthesised with different procedures, are characterised by means of a multi-technique approach and their functionality (electrocatalytic activity in SOCs, reactivity) is investigated. Objective:1) to correlate the observed functionality (electrocatalytic activity, conductivity, etc) with the composition and the synthesis parameters with the strength and surface distribution of active sites; 2) to properly design and optimize ad hoc materials for the different applications.
Both the catalysts and the preparation procedures are selected taking into consideration the economic and environmental sustainability.
Skills
Oxide based materials and nanocomposites functional design.
Optimization of environmentally and economically sustainable synthesis procedures
Nano-material characterization: (XPS, XRD, AFM, SEM, EDX, TGA-DSC, DRIFT, BET, TPD, TPR)
Reactivity investigation (heterogeneous reactions)
Electrocatalytic characterization (EIS)
Hindex 29 (More than 150 contributions: including 117 publications mostly in international peer-reviewed journals, two contributions to edited books, 40 communications)
EUROPEAN EXPERIENCE
Scientific Responsible for UNIPD of
1. European Project: FP7 NMP.2011.2.2-4 - Novel materials for replacement of critical materials (platinum group metals and rare earths)- Collaborative project - "Development of NEXT GENeration cost efficient automotive CATalysts" – 280890
2. European Project: H2020 Development of novel, high Performance hybrid TWV/GPF Automotive afteR treatment systems by raTIonAL design: substitution of PGMs and Rare earth materials – PARTIAL PGM – 686086 - H2020-NMP-2015-
Notices
Office hours
Il docente riceve presso il proprio studio sito in Via F. Marzolo 1, Padova - Piano 3 - su appuntamento
Teachings
- GENERAL AND INORGANIC CHEMISTRY, AA 2024 (FA13101298)
- INORGANIC MATERIALS FOR A SUSTAINABLE DEVELOPMENT, AA 2024 (SCQ2099441)
- GENERAL AND INORGANIC CHEMISTRY, AA 2023 (FA13101298)
- ENGLISH LANGUAGE B2 (PRODUCTIVE SKILLS), AA 2023 (SCP9087619)
- INORGANIC MATERIALS FOR A SUSTAINABLE DEVELOPMENT, AA 2023 (SCQ2099441)
- EDUCATIONAL INTERNSHIP, AA 2023 (SCP5071197)
- GENERAL AND INORGANIC CHEMISTRY, AA 2022 (FA13101298)
- ENGLISH LANGUAGE B2 (PRODUCTIVE SKILLS), AA 2022 (SCP9087619)
- INORGANIC MATERIALS FOR A SUSTAINABLE DEVELOPMENT, AA 2022 (SCQ2099441)
- EDUCATIONAL INTERNSHIP, AA 2022 (SCP5071197)
- CHEMISTRY OF INORGANIC MATERIALS, AA 2021 (SC01122912)
- GENERAL AND INORGANIC CHEMISTRY, AA 2021 (AG19101298)
- GENERAL AND INORGANIC CHEMISTRY, AA 2021 (FA13101298)
- INORGANIC FUNCTIONAL MATERIALS, AA 2021 (SC01122968)
- GENERAL AND INORGANIC CHEMISTRY, AA 2020 (AG19101298)
- INORGANIC FUNCTIONAL MATERIALS, AA 2020 (SC01122968)
- GENERAL AND INORGANIC CHEMISTRY, AA 2019 (AG19101298)
- INORGANIC FUNCTIONAL MATERIALS, AA 2019 (SC01122968)
- GENERAL AND INORGANIC CHEMISTRY, AA 2018 (AG19101298)
- INORGANIC FUNCTIONAL MATERIALS, AA 2018 (SC01122968)
- GENERAL AND INORGANIC CHEMISTRY, AA 2017 (AG19101298)
- INORGANIC FUNCTIONAL MATERIALS, AA 2017 (SC01122968)
- GENERAL AND INORGANIC CHEMISTRY, AA 2016 (AG19101298)
- INORGANIC FUNCTIONAL MATERIALS, AA 2016 (SC01122968)
- GENERAL AND INORGANIC CHEMISTRY, AA 2015 (AG19101298)
- INORGANIC FUNCTIONAL MATERIALS, AA 2015 (SC01122968)
- GENERAL AND INORGANIC CHEMISTRY, AA 2014 (AG19101298)
- INORGANIC FUNCTIONAL MATERIALS, AA 2014 (SC01122968)
- GENERAL AND INORGANIC CHEMISTRY, AA 2013 (AG19101298)
- INORGANIC FUNCTIONAL MATERIALS, AA 2013 (SC01122968)
- GENERAL AND INORGANIC CHEMISTRY, AA 2012 (AG19101298)
- INORGANIC FUNCTIONAL MATERIALS, AA 2012 (SC01122968)
- GENERAL AND INORGANIC CHEMISTRY, AA 2011 (AGN1029470)
- GENERAL AND INORGANIC CHEMISTRY AND BIOCHEMISTRY, AA 2011 (AGN1029469)
- INORGANIC FUNCTIONAL MATERIALS, AA 2011 (SC01122968)
Publications
Rational Development of IT-SOFC Electrodes Based on the Nanofunctionalization of La0.6Sr0.4Ga0.3Fe0.7O3 with Oxides. Part 2: Anodes by Means of Manganite Oxide
J. Cavazzani, A. Bedon, G. Carollo, M. Rieu, J.P. Viricelle, A. Glisenti
ACS Appl. Energy Materials Early 2023
DOI10.1021/acsaem.2c02592
Manganese Based Perovskites in Soot Oxidation: Far from Noble Metals?
E. Brusamarello, G. Peron, F. Nigrelli, A. Glisenti
Topics in Catalysis
DOI 10.1007/s11244-022-01726-y
Early Access NOV 2022
N2 solar activation: ammonia as a hydrogen vector for energy storage
L. Rizzato, J. Cavazzani, A. Osti, A. Glisenti
Faraday Discussions
DOI10.1039/d2fd00147k
Early AccessDEC 2022
Electrochemical study of symmetrical intermediate temperature - solid oxide fuel cells based on La0.6Sr0.4MnO3 / Ce0.9Gd0.1O1.95 for operation in direct methane / air
C. Sanna, E. Squizzato, P. Costamagna, P. Holtappels, A. Glisenti
Electrochimica Acta 2022 DOI 10.1016/j.electacta.2022.139939
Exsolution in Ni-doped lanthanum strontium titanate: a perovskite-based material for anode application in ammonia-fed Solid Oxide Fuel Cell
J. Cavazzani, E. Squizzato, E. Brusamarello, A. Glisenti
Int. J. Hydrogen Energy 2022 DOI 10.1016/j.ijhydene.2022.02.133
Is fighting against pollutants possible with critical raw material free perovskites?
G. Peron, G. Carollo, A. Garbujo, J. Fabro, P. Canu, A. Glisenti
Catalysis Today, 2022 DOI 10.1002/mabi.202000199
Industrially Produced Fe- and Mn-Based Perovskites: Effect of Synthesis on Reactivity in Three-Way Catalysis: Part 1 & 2
E. Brusamarello, C. Blonda, C. Salazar-Castro, A.E. Pascui, P. Canu, A. Glisenti,
Omega 6(38) (2021) 24316-24324and 24325-24337
DOI 10.1021/acsomega.1c02133 10.1021/acsomega.1c02132
Ca2Fe1.95Mg0.05O5: Innovative low cost cathode material for intermediate temperature solid oxide fuel cell
E. Squizzato, G. Carollo, A. Glisenti
Int. J. Hydrogen Energy 2021
DOI 10.1016/j.ijhydene.2021.05.020
Single chamber Solid Oxide Fuel Cells selective electrodes: A real chance with brownmillerite-based nanocomposites
A. Bedon, J.P. Viricelle, M. Rieu, S. Mascotto, A. Glisenti
Int. J. Hydrogen Energy 2021, DOI 10.1016/j.ijhydene.2021.01.220
Cu/CGO cermet based electrodes for Symmetric and Reversible Solid Oxide Fuel Cells
G. Carollo, A. Garbujo, A. Bedon, D. Ferri, M.M. Natile, A. Glisenti
Int. J. Hydrogen Energy 2020
DOI 10.1016/j.ijhydene.2018.01.201
Reversible, all-perovskite SOFCs based on La, Sr gallates(Article)
A. Glisenti, A. Bedon, G. Carollo, C. Savaniu, J.T.S. Irvine
Int. J. Hydrogen Energy 2020 DOI: 10.1016/j.ijhydene.2020.07.142
CuO/La0.5Sr0.5CoO3: Precursor of efficient NO reduction catalyst studied by: Operando high energy X-ray diffraction under three-way catalytic conditions(Article)
I. Alxneit, A. Garbujo, G. Carollo, D. Ferri, A. Glisenti
Phys. Chem. Chem. Phys. 2020 DOI 10.1039/D0CP01064B
Critical Raw Material-Free Catalysts and Electrocatalysts: Complementary Strategies to Activate Economic, Robust, and Ecofriendly SrTiO3
G. Carollo, A. Garbujo, F. Mauvy, A. Glisenti
ENERGY & FUELS 2020 DOI: 10.1021/acs.energyfuels.0c01678
CuO/La0.5Sr0.5CoO3 nanocomposites in TWC
G. Carollo, A. Garbujo, Q. Xin, J. Fabro, P. Cool, P. Canu, A. Glisenti
Appl. Catal B: Environ. 2019 DOI: 10.1016/j.apcatb.2019.117753
Pulsed reactivity on LaCoO3-based perovskites: a comprehensive approach to go inside CO oxidation mechanism and the effect of dopants
D. Pinto, A. Glisenti
Catal. Sci. Techn. 2019 DOI 10.1039/C9CY00210C
Research Area
Research activity focuses on the development of oxide based advanced functional materials. Particular attention is devoted to the green processes with the aim of developing oxide based materials. Research activity mainly concerns design, synthesis and characterization of oxide based nano-materials and nano-composites (perovskites, transition metal oxides, ...) for application in the field of sustainable development (Fuel Cells, pollutants abatement).
1. New Advanced Electrodes for Intermediate Temperature Solid Oxide Fuel Cells (SOFCs) and Solid Oxide Electrolysis Cells (SOECs); our aim is in the development of electrode durable and efficient at intermediate to low temperature, capable of working with different fuels (methane, biogas, ammonia)
2. Platinum Group Metals free catalysts for abatement of pollutants
3. Development of sustainable catalysts for green hydrogen production (dry reforming, water splitting)
4. Catalysts, electrocatalysts, photo-catalysts for the conversion of carbon dioxide in e-fuel and for nitrogen fixation for the sustainable synthesis of ammonia.
Nano-materials, synthesised with different procedures, are characterised by means of a multi-technique approach and their functionality (electrocatalytic activity in SOCs, reactivity) is investigated. Objective:1) to correlate the observed functionality (electrocatalytic activity, conductivity, etc) with the composition and the synthesis parameters with the strength and surface distribution of active sites; 2) to properly design and optimize ad hoc materials for the different applications.
Both the catalysts and the preparation procedures are selected taking into consideration the economic and environmental sustainability.
Thesis proposals
Sustainable energy storage and conversion by means of reversible solid oxide fuel cells
Fuels from carbon dioxide: e-fuels
Ammonia as an hydrogen vector in solid oxide fuel cells
Nitrogen fixation and sustainable synthesis of ammonia
Direct biofuel solid oxide fuel cells
