Address book
Contacts
FEDERICO RASTRELLI
Position
Professore Associato
Structure
Address
VIA F. MARZOLO, 1 - PADOVA
Telephone
0498275279
Federico Rastrelli received a PhD in Chemistry (2005) from the University of Padova, where he currently holds an associate professor position. In the group of prof. Alessandro Bagno he has been working on experimental NMR and quantum chemical calculations of NMR parameters in small diamagnetic and paramagnetic molecules. In the same period he also became interested in applications of NMR spectroscopy in food chemistry.
His present research interests include the design of NMR methods for the investigation of nanosystems, NMR chemosensing techniques and the study of transport phenomena in complex matrices.
Notices
Office hours
Tuesday from 14:30 to 16:00
at Dipartimento di Scienze Chimiche, Via Marzolo 1
Su appuntamento
Teachings
- ORGANIC CHEMISTRY, AA 2024 (FA04101354)
- PHYSICAL METHODS IN ORGANIC CHEMISTRY, AA 2024 (FA02105884)
- PHYSICAL METHODS IN ORGANIC CHEMISTRY, AA 2024 (FA02105884)
- ORGANIC CHEMISTRY, AA 2023 (FA04101354)
- PHYSICAL METHODS IN ORGANIC CHEMISTRY, AA 2023 (FA02105884)
- PHYSICAL METHODS IN ORGANIC CHEMISTRY, AA 2023 (FA02105884)
- ORGANIC CHEMISTRY, AA 2022 (FA04101354)
- PHYSICAL METHODS IN ORGANIC CHEMISTRY, AA 2022 (FA02105884)
- CHEMISTRY AND CERTIFICATION OF FOODSTUFFS, AA 2021 (SCL1000651)
- ORGANIC CHEMISTRY, AA 2021 (FA04101354)
- CHEMISTRY AND CERTIFICATION OF FOODSTUFFS, AA 2020 (SCL1000651)
- ORGANIC CHEMISTRY, AA 2020 (FA04101354)
- CHEMISTRY AND CERTIFICATION OF FOODSTUFFS, AA 2019 (SCL1000651)
- ORGANIC CHEMISTRY, AA 2019 (FA04101354)
- CHEMISTRY AND CERTIFICATION OF FOODSTUFFS, AA 2018 (SCL1000651)
- ORGANIC CHEMISTRY, AA 2018 (FA04101354)
- CHEMISTRY AND CERTIFICATION OF FOODSTUFFS, AA 2017 (SCL1000651)
- CHEMISTRY AND CERTIFICATION OF FOODSTUFFS, AA 2016 (SCL1000651)
- CHEMISTRY AND CERTIFICATION OF FOODSTUFFS, AA 2015 (SCL1000651)
- CHEMISTRY AND CERTIFICATION OF FOODSTUFFS, AA 2013 (SCL1000651)
- CHEMISTRY AND CERTIFICATION OF FOODSTUFFS, AA 2012 (SCO2045656)
Publications
ORCID: http://orcid.org/0000-0002-2369-2228
Schievano, E., Tonoli, M., Rastrelli, F.
NMR Quantification of Carbohydrates in Complex Mixtures. A Challenge on Honey
(2017) Analytical Chemistry, 89 (24), pp. 13405-13414.
DOI: 10.1021/acs.analchem.7b03656
Riccardi, L., Gabrielli, L., Sun, X., De Biasi, F., Rastrelli, F., Mancin, F., De Vivo, M.
Nanoparticle-Based Receptors Mimic Protein-Ligand Recognition
(2017) Chem, 3 (1), pp. 92-109.
DOI: 10.1016/j.chempr.2017.05.016
Casella, G., Causin, V., Rastrelli, F., Saielli, G.
Ionic liquid crystals based on viologen dimers: tuning the mesomorphism by varying the conformational freedom of the ionic layer
(2016) Liquid Crystals, 43 (9), pp. 1161-1173.
DOI: 10.1080/02678292.2016.1161852
González-García, T., Margola, T., Silvagni, A., Mancin, F., Rastrelli, F.
Chromatographic NMR Spectroscopy with Hollow Silica Spheres
(2016) Angewandte Chemie - International Edition, 55 (8), pp. 2733-2737.
DOI: 10.1002/anie.201510203
Rastrelli, F., Bagno, A., Appendino, G., Minassi, A.
Bioactive Phloroglucinyl Heterodimers: The Tautomeric and Rotameric Equilibria of Arzanol
(2016) European Journal of Organic Chemistry, 2016 (28), pp. 4810-4816.
DOI: 10.1002/ejoc.201600597
Diez-Castellnou, M., Salvia, M.-V., Springhetti, S., Rastrelli, F., Mancin, F.
Nanoparticle-Assisted Affinity NMR Spectroscopy: High Sensitivity Detection and Identification of Organic Molecules
(2016) Chemistry - A European Journal, 22 (47), pp. 16957-16963.
DOI: 10.1002/chem.201603578
Salvia, M.-V., Salassa, G., Rastrelli, F., Mancin, F.
Turning Supramolecular Receptors into Chemosensors by Nanoparticle-Assisted "nMR Chemosensing"
(2015) Journal of the American Chemical Society, 137 (35), pp. 11399-11406.
DOI: 10.1021/jacs.5b06300
Borgogno, A., Rastrelli, F., Bagno, A.
Characterization of Paramagnetic Reactive Intermediates: Predicting the NMR Spectra of Iron(IV)-Oxo Complexes by DFT
(2015) Chemistry - A European Journal, 21 (37), pp. 12960-12970.
DOI: 10.1002/chem.201500864
Piserchia, A., Zerbetto, M., Salvia, M.-V., Salassa, G., Gabrielli, L., Mancin, F., Rastrelli, F., Frezzato, D.
Conformational Mobility in Monolayer-Protected Nanoparticles: From Torsional Free Energy Profiles to NMR Relaxation
(2015) Journal of Physical Chemistry C, 119 (34), pp. 20100-20110.
DOI: 10.1021/acs.jpcc.5b04884
Prodi, L., Rampazzo, E., Rastrelli, F., Speghini, A., Zaccheroni, N.
Imaging agents based on lanthanide doped nanoparticles
(2015) Chemical Society Reviews, 44 (14), pp. 4922-4952.
DOI: 10.1039/c4cs00394b
Salvia, M.-V., Ramadori, F., Springhetti, S., Diez-Castellnou, M., Perrone, B., Rastrelli, F., Mancin, F.
Nanoparticle-assisted NMR detection of organic anions: From chemosensing to chromatography
(2015) Journal of the American Chemical Society, 137 (2), pp. 886-892.
DOI: 10.1021/ja511205e
Masseroni, D., Rampazzo, E., Rastrelli, F., Orsi, D., Ricci, L., Ruggeri, G., Dalcanale, E.
pH-responsive host-guest polymerization and blending
(2015) RSC Advances, 5 (15), pp. 11334-11342.
Research Area
NMR methodologies in Organic Chemistry
Matrix-assisted NMR
NMR of nanosystems
Solid-state NMR
Food Chemistry: NMR characterization of oxidation products in vegetable oils. NMR of honey.
Thesis proposals
NMR analysis of complex mixtures
Nuclear Magnetic Resonance (NMR) is a powerful tool for the detection and the analysis of organic compounds in solution. The main advantage of this technique lies in its capability to provide information useful for the structure determination of unknown compounds. Despite this appealing characteristic, the following drawbacks are often encountered in NMR:
• (very) low sensitivity compared to other spectroscopic techniques
• long acquisition times
• high complexity of the spectrum
While the long acquisition times and the sensitivity issues can be quite improved with proper modifications in the pulse sequences, the complexity of the NMR signal is an intrinsic feature of the technique. As such, especially in 1H NMR, it is very common to find overlapped signals in a sample containing two or more analytes, compromising the correct identification of the species.
Further information
http://wwwdisc.chimica.unipd.it/cgi-bin/search/search.pl?Terms=rastrelli
